Leighton Meester's 2012 MTV Movie Awards Arrival

Making a stunning entrance to tonight’s (June 3) festivities, Leighton Meester was spotted arriving at the Gibson Amphitheatre in Los Angeles for the 2012 MTV Movie Awards.

The “Gossip Girl” beauty looked gorgeous in Christian Cota on the red carpet as she posed and smiled for the awaiting photographers before heading inside to get ready to take the stage as one of the night’s many presenters.

Sure to be quite the fun-filled affair, this year's MTV Movie Awards are being hosted by British comedic actor Russell Brand and will boast performances from The Black Keys, fun. and Wiz Khalifa.

Making the night even more memorable, Emma Stone will receive the first annual Trailblazer Award honoring a bright Hollywood newbie while Johnny Depp is set to be honored with the MTV Generation Award for over four decades worth of movie magic.

Enjoy the pictures of Leighton Meester at the 2012 MTV Movie Awards (June 3).